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That styrofoam insulation will work, but it is not cheap per R- value ( however it gives you a great R- value per inch). Insulating an attic usually means you have a lot of room for insulation and you will need high R- value so that is why the cheaper options are more popular ( blown cellulose or blown fiberglass). Expanded Polystyrene ( EPS) Exterior Wall Insulation. The reason EPS is such a good insulating material is the millions of air pockets which are formed when the blocks are molded.
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This report lists a number of commonly used insulating materials found in electronic and electric equipment. Although this listing is somewhat long, it is not comprehensive- the choices available can be. A Guide to Identifying Various Types of Insulation Materials Used in Buildings.